Frenkel line and solubility maximum in supercritical fluids

Frenkel line and solubility maximum in supercritical fluids.

A new dynamic line, the Frenkel line, has recently been proposed to separate the supercritical state into rigid-liquid and nonrigid gaslike fluid. The location of the Frenkel line on the phase diagram is unknown for real fluids. Here we map the Frenkel line for three important systems: CO(2), H(2)O, and CH(4). This provides an important demarcation on the phase diagram of these systems, the dem...

Rutile solubility in supercritical NaAlSi3O8–H2O fluids

Measurement and Modeling of Acridine Solubility in Supercritical Carbon Dioxide

Supercritical carbon dioxide has gained increasing attention in food and pharmaceutical processing owing to the fact that it is environmentally inexpensive, not flammable, essentially non-toxic, and it has a convenient critical point. Also, it has been attracting much attention in many fields, such as extraction of sensitive materials and pharmaceutical processing and polymerization processes. ...

Solubility enhancement in supercritical solvents

The enhancement of solubility of a solid in a supercritical solvent is interpreted with emphasis placed on binary mixtures of the second class. The selection of supercritical solvent ; the choice of temperature and pressure for supercritical fluid extractions; the characteristics of solubility curves between and in the vicinities of the upper critical and the lower critical end points; the effe...

Nucleobases in Supercritical Fluids: Solubility, Molecular Beam Expansion, and Surface Deposition

Supercritical fluids have found applications in a wide variety of fields, from solvents for reaction media to engineering of nanoparticles. They are also of interest in the analytical field for transferring non-volatile organic molecules into the gas phase for detection and deposition purposes. This work highlights the use of supercritical fluids as an analytical tool for the transfer of a grou...